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MATERIAL SAFETY DATA SHEET

BISMUTH

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GENERAL

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COMPANY'S NAME: Huizhou TianYi Rare Material Co.,Ltd

 

COMPANY'S TEL #:    0086-752-2021182

 

COMPANY'S Address:   12K of Shiji, Shijixingtian Bldg, YanDa Road, Huizhou China

 

DATE MSDS PREPARED:  03/05/06

 

DATE MSDS REVISED:   02/12/13

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1. PRODUCT IDENTIFICATION

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PRODUCT NAME:      BISMUTH

CHEMICAL NATURE: METAL

FORMULA:   Bi

 

CAS #:   7440-69-9

 

FORMULA WEIGHT:   208.984

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2. PHYSICAL AND CHEMICAL CHARACTERISTICS

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BOILING POINT 760 mm Hg:   1420-1560 0C

 

MELTING POINT:       271 0C

 

SPECIFIC GRAVITY   9.80 g/cc

VAPOR DENSITY:       N/A

VAPOR PRESSURE:   1mm at 1020oC

% VOLATILES:    N/A OR N/E

SOLUBILITY IN H2O: INSOLUBLE

APPEARANCE AND ODOR:     GRAY METALLIC POWDERS,SHOTS, NEDDLES, GRANULES

 

CHUNKS ODORLESS

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3. HAZARD IDENTIFICATION

 

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HAZARD DESCRIPTION:  F HIGHLY FLAMMABLE

RISK PHRASES:  R 11 HIGHLY FLAMMABLE

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4. FIRE FIGHTING MEASURES

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FLASH POINT:     N/A OR N/E  

AUTOIGNITION TEMPERATURE:   N/A

FLAMMABLE LIMITS:             

UPPER: N/E

LOWER:       N/E

FLAMMABILITY:  NON-FLAMMABLE SOLID      

EXTINGUISHING MEDIA:  USE CLASS D OR OTHER SUITABLE METAL    

SPECIAL FIRE FIGHTING EXTINGUISHING AGENT 

             

PROCEDURES:   FIREFIGHTERS MUST WEAR FULL FACE, SELF-CONTAINED    

       BREATHING APPARATUS AND FULL PROTECTIVE 

       CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.

       FUMES FROM FIRE ARE HAZARDOUS. ISOLATE RUNOFF  

UNUSUAL FIRE AND  TO PREVENT ENVIRONMENTAL POLLUTION. 

             

EXPLOSION HAZARDS:    FLAMMABLE WHEN EXPOSED TO FLAME. MAY REACT      

       WITH ACID OR ACID FUMES TO EMIT TOXIC FUMES. MAY 

 

REACT WITH [BI(OH)3 + AL(OH)3 COPRECIPITATED, AND HYDROGEN TO PRODUCE A SPONTANEOUSLY FLAMMABLE PRODUCT. SUPERFICIALLY OXIDIZED BY AIR. MAY RELEASE METAL OXIDE FUME

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5. HEALTH HAZARD INFORMATION

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EFFECTS OF EXPOSURE:      BISMUTH AND ITS SALTS CAN CAUSE KIDNEY DAMAGE,   

       ALTHOUGH THE DEGREE OF SUCH DAMAGE IS USUALLY 

       MILD. LARGE DOSES CAN BE FATAL. INDUSTRIALLY IT IS  

       CONSIDERED ONE OF THE LESS TOXIC OF THE HEAVY    

       METALS. SERIOUS AND SOMETIMES FATAL POISONING    

       MAY OCCUR FROM THE INJECTION OF LARGE DOSES INTO   

       CLOSED CAVITIES AND FROM EXTENSIVE APPLICATION   

       TO BURNS. IT IS STATED THAT THE ADMINISTRATION OF 

       BISMUTH SHOULD BE STOPPED WHEN GINGIVITIS     

       APPEARS, FOR OTHERWISE SERIOUS ULCERATION   

       STOMATITIS IS LIKELY TO RESULT. OTHER TOXIC      

       RESULTS MAY DEVELOP, SUCH AS A VAGUE FEELING OF  

       BODILY DISCOMFORT, PRESENCE OF ALBUMIN OR OTHER     

       PROTEIN SUBSTANCE IN THE URINE, DIARRHEA, SKIN      

       REACTIONS AND SOMETIMES SERIOUS EXODERMATITIS.

       (SAX, DANGEROUS PROPERTIES OF INDUSTRIAL

ACUTE EFFECTS:     MATERIALS, EIGHTH EDITION     

             

INHALATION: POISON.     MAY BE A NUISANCE DUST CAUSING RESPIRATORY   

       IRRITATION. MAY CAUSE FOUL BREATH, METALLIC     

INGESTION: POISON.      TASTE AND GINGIVITIS. 

       MAY CAUSE MALAISE, ALBUMINURIA, DIARRHEA, SKIN      

       REACTIONS, STOMATITIS, HEADACHE, FEVER,    

       RHEUMATIC PAIN AND A BLACK LINE MAY FORM ON   

       GUMS IN THE MOUTH.   

SKIN:     MAY CAUSE IRRITATION 

EYE:      MAY CAUSE IRRITATION 

INHALATION:      MAY AFFECT THE FUNCTION OF THE LIVER AND THE

       KIDNEYS.    

INGESTION: MAY AFFECT THE FUNCTION OF THE LIVER AND 

       KIDNEYS. MAY CAUSE ANEMIA and black line May form ON  

       GUMS AND ULCERATIVE STOMATITIS.     

SKIN:     MAY CAUSE DERMATITIS.     

EYE:      NO CHRONIC HEALTH EFFECTS RECORDED.

TARGET ORGANS:    MAY AFFECT THE KIDNEYS AND LIVER.   

MEDICAL CONDITIONS GENERALLY         

AGGRAVATED BY EXPOSURE:      PRE-EXISTING SKIN AND RESPIRATORY DISORDERS  

ROUTES OF EXPOSURE: INHALATION, SKIN, AND INGESTION  

CARCINOGENITY:           

NTP:      NO 

IARC:     NO 

OSHA:   NO 

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6. STABILITY

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STABILITY:   STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINER.     

CONDITION TO AVOID:    HEAT, FLAME, INCOMPATIBLE MATERIALS, IGNITION  

INCOMPATIBILITY     SOURCES AND STRONG OXIDANTS.        

       ALUMINUM, BRF3, ACIDS, NOF, NH4NO3, HC1O     3, CL2, IF5, 

(MATERIAL TO AVOID):                 

HAZARDOUS      HNO3, HCLO4, OXIDANTS.           

                    

DECOMPOSITION PRODUCTS:     BISMUTH OXIDES           

HAZARDOUS                   

POLYMERIZATION:    WILL NOT OCCUR.          

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7. EMERGENCY AND FIRST AID PROCEDURES:

 

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INHALATION:      REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT

 

GIVE OXYGEN. SEEK MEDICAL ATTENTION

INGESTION: ADMINISTER 1-2 GLASSES OF MILK OR WATER AND

INDUCE VOMITING. SEEK MEDICAL ATTENTION. NEVER

GIVE ANYTHING BY MOUTH OR INDUCE VOMITING IN AN

 

UNCONSCIOUS PERSON

SKIN:     BRUSH MATERIAL OFF SKIN AND WASH AREA WITH SOAP

AND WATER. SEEK MEDICAL ATTENTION IF SYMPTOMS

 

PERSIST.

EYE:      FLUSH EYES WITH LUKEWARM WATER FOR AT LEAST 15

MINUTE. SEEK MEDICAL ATTENTION IF SYMPTOMS

 

PERSIST.

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8. HANDLING AND STORAGE

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HANDLING AND STORAGE     STORE IN TIGHTLY CLOSED CONTAINERS IN A COOL, DRY

PLACE AWAY FROM HEAT AND FLAME.. STORE AWAY

FROM INCOMPATIBLE MATERIALS. WASH HANDS AND

FACE THOROUGHLY AFTER HANDLING AND BEFORE

 

MEALS.

OTHER PRECAUTIONS:   AVOID CONTACT TO SKIN AND EYES. AVOID CONTACT

WITH HEAT, SPARKS AND FLAME. AVOID INGESTION

 

ANDINHALATION.

 

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9. SPILL OR LEAK PROCEDURES

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STEPS TO BE TAKEN IN         

CASE MATERIAL IS          

RELEASED OR SPILLED: WEAR APPROPRIATE RESPIRATORY AND PROTECTIVE     

       EQUIPMENT SPECIFIED IN SECTION VIII. ISOLATE SPILL,  

       INSURE PROPER VENTILATION AND EXTINGUISH 

       SOURCES OF IGNITION. VACUUM UP SPILL USING A HIGH

       EFFICIENCY PARTICULATE ABSOLUTE (HEPA) AIR FILTER 

       AND PLACE IN A CONTAINER FOR PROPER DISPOSAL.      

       TAKE CARE NOT TO RAISE DUST. USE NON-SPARKING      

       TOOLS.

WASTE DISPOSAL METHOD:  IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL 

RESPIRATORY PROTECTION REGULATIONS. 

             

(SPECIFY TYPE):       WEAR A NIOSH-APPROVED DUST-MIST-FUME CARTRIDGE      

       RESPIRATOR.    

VENTILATION:    USE LOCAL EXHAUST TO MAINTAIN CONCENTRATION AT 

       LOW EXPOSURE LEVELS. HANDLE POWDERS IN A      

       CONTROLLED, ENCLOSED ENVIRONMENT. GENERAL

       EXHAUST IS NOT RECOMMENDED.   

PROTECTIVE GLOVES:    RUBBER GLOVES     

EYE PROTECTION:   SAFETY GLASSES    

OTHER PROTECTIVE EQUIPMENT:     PROTECTIVE GEAR SUITABLE TO PREVENT  

       CONTAMINATION.    

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10. TOXICITY DATA

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METALLIC BISMUTH IS RELATIVELY NON-TOXIC

ORAL RAT LD50: 5g/Kg

ORAL MOUSE:    10gm/kg

CARCINOGENICITY:

ACGIH:  NO

IARC:     NO

NIOSH:  NO

 

NTP:      NO

 

OSHA:   NO

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11. TRANSPORTATION DATA

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POWDER DOT REGULATED:

PRPPER SHIPPING NAME:      METAL POWDER, FLAMMABLE, N.O.S. (BISMUTH POWDER)

HAZARD CLASS: 4.1

PACKING GROUP:     III

UN NUMBER:      3089

ADR//RID CLASS:       4.1 (F3) FLAMMABLE SOLIDS, SELF-REACTIVE SUBSTANCES

AND SOLID DESINSITISED EXPLOSIVES

IMDG CLASS:      4.1

AIR TRAN. ICAO/IATA CLASS: 4.1

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12. OTHER INFORMATION

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THIS SAFETY DATA SHEET SHOULD BE USED IN CONJUNCTION WITH TECHNICAL SHEETS. IT DOES NOT REPLACE THEM. THE INFORMATION GIVEN IS BASED ON OUR KNOWLEDGE OF THIS PRODUCT, AT THE TIME OF PUBLICATION. IT IS GIVEN IN GOOD FAITH. THE ATTENTION OF THE USER IS DRAWN TO THE POSSIBLE RISKS INCURRED BY USING THE PRODUCT FOR ANY OTHER PURPOSE OTHER THAN THAT FOR WHICH IT WAS INTENDED. THIS DOES NOT IN ANY WAY EXCUSE THE USER FROM KNOWING AND APPLYING ALL THE REGULATIONS GOVERNING HIS ACTIVITY. IT IS THE SOLE RESPONSIBILITY OF THE USER TO TAKE ALL PRECAUTIONS REQUIRED IN HANDLING THE PRODUCT. THE AIM OF THE MANDATORY REGULATIONS MENTIONED IS TO HELP THE USER TO FULFILL HIS OBLIGATIONS REGARDING THE USE OF HAZARDOUS PRODUCTS.