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BiFeO3

MATERIAL SAFETY DATA SHEET

 

BISMUTH IRON OXIDE

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GENERAL

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COMPANY'S NAME: Huizhou TianYi Rare Material Co.,Ltd

 

COMPANY'S TEL #:    0086-752-2021182

 

COMPANY'S Address:   12K of Shiji, Shijixingtian Bldg, YanDa Road, Huizhou China    

 

DATE MSDS PREPARED:  03/05/06

 

DATE MSDS REVISED:   02/12/13

 

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1. PRODUCT IDENTIFICATION

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PRODUCT NAME: BISMUTH IRON OXIDE

FORMULA:       BiFeO3

 

CAS #: 1304-76-3/1309-37-1

 

MOLECULAR WEIGHT:      312.83

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2. PHYSICAL AND CHEMICAL CHARACTERISTICS

 

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BOILING POINT:     N/A

 

MELTING POINT:    N/A

SPECIFIC GRAVITY (H2O=1):  N/A

 

VAPOR DENSITY: N/A

 

VAPOR PRESSURE:   N/A

 

EVAPORATION RATE N/A

 

% VOLATILES: N/A

SOLUBILITY IN H2O:    INSOLUBLE

 

APPEARANCE AND ODOR:    REDDISH BROWN SPUTTERING TARGET

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3. HAZARD IDENTIFICATION

 

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HAZARD DESCRIPTION:   Xi IRRITANT    

RISK PHRASES:    36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM, AND  

HMIS RATINGS:     SKIN    

             

HEALTH:    1    

FLAMMABILITY:     0    

REACTIVITY:    0    

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4. FIRE FIGHTING MEASURES

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FLASH POINT: N/A

 

AUTOIGNITION TEMPERATURE:  N/A

 

FLAMMABLE LIMITS:

 

UPPER:      N/A

 

LOWER:     N/A

EXTINGUISHING MEDIA:   PRODUCT IS NOT FLAMMABLE. USE FIREFIGHTING

MEASURES THAT SUIT THE CURROUNDING FIRE.

SPECIAL HAZARDS:   IN CASE OF A FIRE, METAL OXIDE FUMES MAY BE

RELEASED

 

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5. HEALTH HAZARD INFORMATION

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ACUTE EFFECTS:

 

SKIN:    POWDER: IRRITATING TO SKIN AND MUCOUS

 

MEMBRANES

EYE:     POWDER: IRRITATING EFFECT

CHRONIC EFFECTS:   BISMUTH AND BISMUTH COMPOUNDS ARE OFTEN

POORLY ABSORBED. SHOULD ABSORPTION OCCUR,

HOWEVER, EXPOSURE MAY CAUSE LOSS OF APPETITE,

HEADACHE, SKIN RASH, EXODERMATITS, KIDNEY

INJURY, AND JAUNDICE. REPEATED OR PROLONGED

EXPOSURE MAY CAUSE A BISMUTH LINE OR BLACK

SPOTS ON TE GUMS, FOUL BREATH, AND SALIVATION.

TUMORIGENIC EFFECTS OF IRON OXIDE HAVE BEEN

OBSERVED IN LABORATORY ANIMALS.

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6. STABILITY

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STABILITY:       STABLE

 

CONDITIONS TO AVOID:   NONE

 

MATERIAL TO AVOID: OXIDIZING AGENTS, ACIDS

 

DANGEROUS REACTIONS:    NONE KNOWN

 

HAZARDOUS

 

DECOMPOSITION PRODUCTS:     METAL OXIDE FUMES

 

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7. EMERGENCY AND FIRST AID PROCEDURES:

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INHALATION:   REMOVE TO FRESH AIR AND PROVIDE ARTIFICIAL

RESPIRATION IF NECESSARY. SEEK IMMEDIATE MEDICAL

ADVICE.

 

INGESTION:     SEEK IMMEDIATE MEDICAL ATTENTION.

SKIN:    WASH SKIN THOROUGHLY WITH MILD SOAP AND WATER.

RINSE THOROUGHLY. SEEK IMMEDIATE MEDICAL

 

ADVICE.

EYE:     FLUSH EYES WITH PLENTY OF WATER. SEEK IMMEDIATE

MEDICAL ADVICE.

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8. HANDLING AND STORAGE

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HANDLING & STORAGE:   STORE IN A COOL, DRY PLACE IN TIGHTLY SEALED

CONTAINERS. ENSURE GOOD VENTILATION. NO SPECIAL

REQUIREMENTS ARE NECESSARY IF USED CORRECTLY.

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9. SPILL OR LEAK PROCEDURES

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STEPS TO BE TAKEN IN

 

CASE MATERIAL IS

 

RELEASED OR SPILLED:

 

RESPIRATION:       WEAR NIOSH APPROVED DUST-MIST VAPOR RESPIRATOR.

VENTILATION: LOCAL EXHAUST TO MAINTAIN CONCENTRATION AT OR

BELOW THE PEL, TLV.

 

PROTECTIVE GLOVES:     RUBBER GLOVES.

 

EYE PROTECTION:      SAFETY GLASSES

PROTECTIVE CLOTHING: PROTECTIVE GEAR SUITABLE TO PREVENT

CONTAMINATION.

WASTE DISPOSAL METHOD: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND

FEDERAL REGULATIONS.

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10. TOXICITY DATA

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LD/LD50 VALUES:

ORAL:  LD50: 10 gm/kg (MOUSE)

LD50: 5 gm/kg (RAT)

THE REGISTRY OF TOXIC EFFECTS OF

CHEMICAL SUBSTANCES REPORTS

THE FOLLOWING EFFECTS IN

 

LABORATORY ANIMALS:  BLOOD- METHOGLOBINEMIA-CARBOXYHEMOGLOBIN;

       CAHNGES IN SERUM COMPOSITIOIN     

       BRAIN AND COVERINGS – OTHER DEGENERATIVE CHANGES     

       BIOCHEMICAL – ENZYME INHIBITION, INDUCTION, OR 

       CHANGE IN BLOOD TISSUE LEVELS – TRUE CHOLINSTERASE     

       TUMORIGENIC – EQUIVOCAL TUMORIGENIC AGENTS BY  

CARCINOGENICITY:    RTECS CRITERIA; TUMORS AT SITE OF APPLICATION  

             

BISMUTH OXIDE:   NO CLASSIFICATION DATA ON CARCINOGENIC PROPERTIES

       OF THIS MATERIAL IS AVAILABLE FROM THE EPA, IARC,   

       NTP, OSHA, OR ACGIH.    

IRON OXIDE:    IARC-3: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO 

       HUMANS  

       ACGIH A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN –  

       INADEQUATE DATA ON WHICH TO CLASSIFY THE AGENT IN   

       TERMS OF ITS CARCINOGENICTY IN HUMANS AND/OR      

       ANIMALS  

ADDITIONAL INFORMATION:  TO THE BEST OF OUR KNOWLEDGE THE ACUTE AND 

       CHRONIC TOXICITY OF THIS SUBSTANCE IS NOT FULLY   

KNOWN.

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11. TRANSPORTATION DATA

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UN NUMBER:  NONE

HAZARD CLASS:   NONE

ADR//RID CLASS:  NONE

IMDG CLASS:  NONE

ICAO/IATA CLASS:       NONE

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12. OTHER INFORMATION

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THIS SAFETY DATA SHEET SHOULD BE USED IN CONJUNCTION WITH TECHNICAL SHEETS. IT DOES NOT REPLACE THEM. THE INFORMATION GIVEN IS BASED ON OUR KNOWLEDGE OF THIS PRODUCT, AT THE TIME OF PUBLICATION. IT IS GIVEN IN GOOD FAITH. THE ATTENTION OF THE USER IS DRAWN TO THE POSSIBLE RISKS INCURRED BY USING THE PRODUCT FOR ANY OTHER PURPOSE OTHER THAN THAT FOR WHICH IT WAS INTENDED. THIS DOES NOT IN ANY WAY EXCUSE THE USER FROM KNOWING AND APPLYING ALL THE REGULATIONS GOVERNING HIS ACTIVITY. IT IS THE SOLE RESPONSIBILITY OF THE USER TO TAKE ALL PRECAUTIONS REQUIRED IN HANDLING THE PRODUCT. THE AIM OF THE MANDATORY REGULATIONS MENTIONED IS TO HELP THE USER TO FULFILL HIS OBLIGATIONS REGARDING THE USE OF HAZARDOUS PRODUCTS.