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GaSb

 

 

MATERIAL SAFETY DATA SHEET

GALLIUM ANTIMONIDE, GaSb

 

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GENERAL

 

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COMPANY'S NAME: Huizhou TianYi Rare Material Co.,Ltd

 

COMPANY'S TEL #:    0086-752-2021182

 

COMPANY'S Address:   12K of Shiji, Shijixingtian Bldg, YanDa Road, Huizhou China      

 DATE MSDS PREPARED:       04/08/06

 

DATE MSDS REVISED:                   02/11/13

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1. IDENTIFICATION

 

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TRADE NAME:           GALLIUM ANTIMONIDE   

SYNONYM:          GALLIUM MONOANTIMONIDE      

MOLECULAR WEIGHT:     191.47         

FORMULA:                       

              GaSb           

CAS #:          12064-03-8         

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       2. HAZARDOUS INGREDIENTS     

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HAZARD DESCRIPTION:                      

              Xn HARMFUL     

              N DANGEROUS FOR THE ENVIRONMENT

 

 

INFORMATION PERTAINING TO PARTICULAR DANGERS FOR MAN AND ENVIRONMENT:

 

 

 R 20/22 HARMFUL BY INHALATION AND IF SWALLOWED.

 

R 51/53 TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.

 

 

 

HAZARDOUS COMPONENT%

 

 

GALLIUM ANTIMONIDE (0-100%)

 

 

OSHA/PEL:   0.01 (As) mg/m3

 

 

ACGIH/TLV:  0.01 (As) mg/m3

 

 

HMIS RATINGS (0-4):

 

 

HEALTH:       3

 

 

 

FLAMMABILITY:  0

 

REACTIVITY:       1

 

 

 

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3. PHYSICAL DATA

 

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BOILING POINT:  N/A

 

 

MELTING POINT:       710oC

 

 

VAPOR DENSITY:       N/A

 

 

% VOLATILES:    N/A

 

SPECIFIC GRAVITY:  N/A

 

 

SOLUBILITY IN H2O: INSOLUBLE

 

 

 

APPEARANCE AND ODOR: DARK GRAY, BALCK, GRANULES, TARGET, ODORLESS

 

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4. FIRE AND EXPLOSION HAZARDS DATA

 

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FLASH POINT:     N/A

AUTOIGNITION TEMPERATURE:   N/A

FLAMMABLE LIMITS:             

UPPER: N/A

LOWER:       N/A

FLAMMABILITY:  NON-FLAMMABLE SOLID      

EXTINGUISHING MEDIA:  USE DRY CHEMICAL, CO2 OR GRAPHITE. DO NOT      

SPECIAL FIREFIGHTING  USE WATER OR WATER SPRAY    

             

PROCEDURES:   WEAR NIOSH/MSHA APPROVED SELF-CONTAINED      

       BREATHING APPARATUS, FLAME AND CHEMICAL 

UNUSUAL FIRE & EXPLOSION       RESISTANT CLOTHING, HATS, BOOTS, AND GLOVES.  

             

HAZARD:      NONE.  

 

 

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5. HEALTH HAZARD INFORMATION

 

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EFFECTS OF OVER EXPOSURE:  ANTIMONY COMPUNDS MAY CAUSE METALLIC    

       TASTE, GASTOINTESTINAL DISTURBANCES,  

       VOMITING, DIARRHEA, DIZZINESS AND SYSTEMIC      

       POISONING. CHRONIC EXPOSURE MAY CAUSE     

       LIVER AND KIDNEY DAMAGE. DERMATITS AND     

       ECZEMATOUS SKIN ERUPTIONS MY RESULT FROM    

       SKIN CONTACT. GALLIUM AND GALLLIUM

       COMPUNDS MAY CAUSE METALLIC TASTE,    

       DERMATITS AND DEPRESSIONS OF THE BONE     

       MARROW FUNCTIONS. LARGE DOSES MAY CAUSE     

ACUTE EFFECTS:     HEMORRHAGIC NEPHRITIS. 

             

INHALATION:      MAY BE FATAL IF INHALED    

INGESTION: MAY BE FATAL. EVIDENCE SUGGESTS LOW   

       TOXICITY POTENTIAL DUE TO POOR ABSORPTION     

       BY THE ORAL ROUTE.    

SKIN:     MAY CAUSE IRRITATION.

EYE:      MAY CAUSE EYE IRRITATION.      

ROUTE OF ENTRY:   INHALATION, SKIN, INGESTION   

CARCINOGENICITY:        

NTP:      NO 

IARC:     NO 

OSHA:   YES      

ACGIH:  YES      

 

 

 

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6. EMERGENCY & FIRST AID PROCEDURES

 

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INHALATION:      REMOVE TO FRESH AIR; GIVE OXYGEN IF

 

 

BREATHING IS DIFFICULT. SEEK MEDICAL

 

ATTENTION.

 

INGESTION: GIVE 2 CUPS OF MILK OR WATER AND INDUCE

 

 

VOMITING. SEEK MEDICAL ATTENTION.

 

 

SKIN:     BRUSH OFF SKIN, WASH AREA WITH SOAP AND

 

 

WATER. SEEK MEDICAL ATTENTION.

 

EYES:    IMMEDIATELY FLUSH EYES, INCLUDING UNDER

 

EYELIDS WITH LARGE AMOUNTS OF WATER. CALL

 

 

A PHYSICIAN.

 

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7. REACTIVITY DATA

 

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STABILITY:   STABLE

 

CONDITIONS TO AVOID:  NONE.

 

INCOMPATIBILITY

 

(MATERIALS TO AVOID):  BASES, ACIDS, OXIDIZING AGENTS.

 

HAZARDOUS DECOMPOSITION

 

PRODUCTS OR BYPRODUCTS:    TOXIC METAL OXIDE FUME

 

HAZARDOUS POLYMERIZATION:  WILL NOT OCCUR.

 

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8. SPILL OR LEAK PROCEDURES

 

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STEPS TO BE TAKEN IN CASE                          

MATERIAL IS RELEASED                      

OR SPILLED:       WEAR FULL PROTECTIVE EQUIPMENT, COVER     

       SPILL WITH DRY SAND OR VERMICULITE. MIX      

       WELL AND CAREFULLY TRANSFER TO A  

                           

RESPIRATORY PROTECTION CONTAINER.             

                           

(SPECIFY TYPE):       WEAR A NIOSH-  APPROVED DUST-MIST-FUME     

       CARTRIDGE RESPIRATOR.   

VENTILATION:    HANDLE UNDER DRY PROTECTIVE GAS. HANDLE

       IN A CONTROLLED ENVIRONMENT. USE LOCAL    

       EXHAUST TO MAINTAIN BELOW TLV LEVEL FOR   

       ARSENIC.    

EYE PROTECTION:   ANSI APPROVED SAFETY GOGGLES, OR GLASSES.    

PROTECTIVE GLOVES:    NEOPRENE, RUBBER      

OTHER PROTECTIVE EQUIPMENT:     WEAR PROTECTIVE CLOTHING TO PREVENT

       CONTAMINATION OF SKIN AND CLOTHES.      

WASTE DISPOSAL METHOD:  DISPOSE OF IN ACCORDANCE WITH LOCAL, TATE      

       AND FEDERAL REGULATIONS.    

 

 

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9. HANDLING AND STORAGE

 

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HANDLING AND STORAGE:    HANDLE UNDER DRY PROTECTIVE GAS. PROTECT

 

FROM HUMIDITY AND WATER. STORE IN TIGHTLY

 

 

CLOSED CONTAINERS IN A COOL, DRY PLACE. WASH

 

HANDS AND FACE THOROUGHLY AFTER HANDLING

 

 

AND BEFORE MEALS

 

 

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10. TOXICOLOGICAL INFORMATION

 

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TO THE BEST OF OUR KNOWLEDGE THE ACUTE AND CHRONIC TOXICITY OF THE SUBSTANCE IS NOT FULLY KNOWN.

 

ACUTE TOXICITY:

 

 

IRRITANT:     SKIN, MUCUS MEMBRANE, EYE

 

SENSITIZATION: NONE

 

 

SUBACUTE TO CHRONIC:      ACUTE ARSENIC POISONING FROMINGESTION

 

 

RESULTS IRRITATION OF THE STOMACH AND

 

 

       INTESTINE WITH NAUSEA, VOMITING AND     

       DIARRHEA, BLOODY STOOL, THREADY PULSE,    

       COMA AND DEATH.  

       CHRONIC ARSENIC POISONING MAY CAUSE  

       DIGESTIVE TRACT UPSET, CRAMPS, NAUSEA,      

       CONSTIPATION OR DIARRHEA.   

       GALLIUM COMPONENT MAY CAUSE METALLIC     

       TASTE, DERMATITIS, AND DEPRESSION OF BONE

       MARROW FUNCTION AND ALSO MAY CAUSE  

CARCINOGENICITY:  NEPHRITIS. 

             

IARC:     NO 

NTP:      NO 

OSHA:   YES      

ACGIH:  YES      

 

 

 

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11. TRANSPORTATION DATA

 

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DOT REGULATED FOR POWDERS AND PIECES:

 

SHIPPING NAME:       ANTIMONY COMPUND, INORGANIC, SOLID, N.O.S

HAZARD CLASS: 6.1        

UN#       1549            

PACKAGING GROUP:       III                 

                           

RAIL/ROAD (RID/ADR):     6.1 (T5) TOXIC    SUBSTANCES    

MARITIME TRANSPORT (IMO/MDG):   6.1        

                           

AIR TRANSPORT (ICAO-IATA):      6.1        

 

 

 

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13. OTHER INFORMATION

 

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THIS SAFETY DATA SHEET SHOULD BE USED IN CONJUNCTION WITH TECHNICAL SHEETS. IT DOES NOT REPLACE THEM. THE INFORMATION GIVEN IS BASED ON OUR KNOWLEDGE OF THIS PRODUCT, AT THE TIME OF PUBLICATION. IT IS GIVEN IN GOOD FAITH. THE ATTENTION OF THE USER IS DRAWN TO THE POSSIBLE RISKS INCURRED BY USING THE PRODUCT FOR ANY OTHER PURPOSE OTHER THAN THAT FOR WHICH IT WAS INTENDED. THIS DOES NOT IN ANY WAY EXCUSE THE USER FROM KNOWING AND APPLYING ALL THE REGULATIONS GOVERNING HIS ACTIVITY. IT IS THE SOLE RESPONSIBILITY OF THE USER TO TAKE ALL PRECAUTIONS REQUIRED IN HANDLING THE PRODUCT. THE AIM OF THE MANDATORY REGULATIONS MENTIONED IS TO HELP THE USER TO FULFILL HIS OBLIGATIONS REGARDING THE USE OF HAZARDOUS PRODUCTS.