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SnO2

MATERIAL SAFETY DATA SHEET

 

TIN OXIDE

 

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GENERAL

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COMPANY'S NAME: Huizhou TianYi Rare Material Co.,Ltd

 

 

COMPANY'S TEL #:    0086-752-2021182

 

 

COMPANY'S Address:   12K of Shiji, Shijixingtian Bldg, YanDa Road, Huizhou China    

 

DATE MSDS PREPARED: 03/05/06

 

DATE MSDS REVISED:          02/12/13

 

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1. PRODUCT IDENTIFICATION

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PRODUCT NAME: TIN OXIDE

SYNONYM:       STANNIC OXIDE, STANNIC ANHYDRIDE, CASSITERITE

CHEMICAL NATURE:  METAL OXIDE

FORMULA:       SnO2, SnOx, SnO

FORMULA Weight: 150.71

CAS #: 18282-10-5 (GRANULES AND POWDER

21651-19-4 (TARGET)

 

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2. PHYSICAL AND CHEMICAL CHARACTERISTICS

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BOILING POINT      1800 - 19000C (SUBLIMES)

MELTING POINT:    16300C

DENSITY:   6.95

 

VAPOR DENSITY: N/A

 

VAPOR PRESSUR (MM Hg):    N/A

% VOLATILES: 0

SOLUBILITY IN H2O:    INSOLUBLE

APPEARANCE AND ODOR:    BLUISH WHITE, DARK GRAY, BLACK POWDER,

GRANULES, SPUTTERING TARGETS, INGOTS, RODS ETC.

 

ODORLESS

 

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3. HAZARD IDENTIFICATION

 

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HAZARDOUS COMPONENTS %  

TIN 0-100%

OSHA/PEL:       2 mg/m3

ACGIH/TLV       2 mg/m3

HMIS RATINGS:    

HEALTH:    1

FLAMMABILITY:     0

REACTIVITY:    0

PROTECTIVE EQUIPMENT:     F: GLASSES, GLOVES, APRON, DUST MASK.

 

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4. FIRE FIGHTING MEASURES

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FLASH POINT (METHOD USED):   N/A      

AUTOIGNITION TEMPERATURE:  NO DATA  

FLAMMABLE LIMITS:         

UPPER:      N/A      

LOWER:     N/A      

FLAMMABILITY:     NON-FLAMMABLE      

EXTINGUISHING MEDIA:   NON-COMBUSTIBLE, USE EXTINGUISHING MEDIA 

SPECIAL FIRE FIGHTING  APPROPRIATE FOR SURROUNDING FIRE.  

             

 

PROCEDURES:     USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT   

UNUSUAL FIRE AND  APPROPRIATE FOR THE SURROUNDING FIRE.

             

EXPLOSION HAZARDS:    NONE IDENTIFIED.     

 

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5. HEALTH HAZARD INFORMATION

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EFFECTS OF OVER EXPOSURE:

 

ACUTE EFFECTS:

 

INGESTION:     MAY CAUSE NAUSEA, VOMITING AND DIARRHEA.

 

INHALATION:   MAY CAUSE IRRITATION TO RESPIRATORY TRACT LEADING

TO COUGH AND SHORTNESS OF BREATH

SKIN:    MAY CAUSE IRRITATION WITH REDNESS AND PAIN

EYE:     MAY CAUSE IRRITATION WITH REDNESS AND PAIN.

CHRONIC EFFECTS:   INHALATION OF DUST MAY CAUSE PNEUMOCONIOSIS.

 

ROUTES OF EXPOSURE: MOST LIKELY INGESTION.

OTHER HEALTH HAZARDS:   NONE KNOWN.

CARCINOGENITY:

 

NTP:     NO

 

IARC:   NO

 

OSHA:  NO

 

EPA:     NO

 

MEDICAL CONDITIONS

 

GENERALLY AGGRAVATED

BY EXPOSURE:     PERSON WITH RESPIRATORY PROBLEM MAY BE MORE

PRONE TO EFFECT.

 

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6. STABILITY

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STABILITY:       STABLE UNDER NORMAL CONDITIONS 

CONDITION TO AVOID:      NONE 

INCOMPATIBILITY       

(MATERIAL TO AVOID):      CHLORINE TRIFLUORIDE, HYDROGEN TRISULFIDE,    

HAZARDOUS  MAGNESIUM, POTASSIUM, SODIUM.

             

DECOMPOSITION PRODUCTS:     NO DATA. 

HAZARDOUS        

POLYMERIZATION:      WILL NOT OCCUR.      

 

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7. EMERGENCY AND FIRST AID PROCEDURES:

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INGESTION:     INDUCE VOMITING IMMEDIATELY AS DIRECTED BY

MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH

TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.

INHALATION:   REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR

ANY BREATHING DIFFICULTY.

SKIN:    REMOVE CONTAMINATED CLOTHING, FLOOD SKIN WITH

LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS SEEK

MEDICAL ATTENTION.

EYE:     IMMEDIATELY FLUSH EYES, INCLUDING UNDER EYELIDS,

WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15

MINUTES. CALL A PHYSICIAN.

 

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8. HANDLING AND STORAGE

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HANDLING AND STORAGE     KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL,

DRY, WELL-VENTILATED AREA. WASH THOROUGHLY

 

AFTER USE.

 

OTHER PRECAUTIONS:    USE LAB COAT AND APRON, FLAME AND CHEMICAL

 

RESISTANT COVERALLS, EYEWASH CAPABLE OF

SUSTAINED FLUSHING, SAFETY DRENCH SHOWER AND

 

HYGIENIC FACILITIES FOR WASHING.

 

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9. SPILL OR LEAK PROCEDURES

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STEPS TO BE TAKEN IN          

CASE MATERIAL IS           

RELEASED OR SPILLED: WEARING FULL PROTECTIVE EQUIPMENT, COVER SPILL 

       WITH DRY SAND OR VERMICULITE.MIX WELL AND

RESPIRATORY PROTECTION       CAREFULLY TRANSFER TO A CONTAINER.

             

(SPECIFY TYPE):   HIGH EFFICIENCY PARTICLE RESPIRATOR.      

VENTILATION: LABORATORY FUME HOOD. 

PROTECTIVE GLOVES:     RUBBER GLOVES.     

EYE/FACE PROTECTION: ANSI APPROVED SAFETY GLASSES.     

PROTECTIVE CLOTHING: CHEMICAL RESISTANT COVERALLS, LAB COAT OR     

APRON.            

WASTE DISPOSAL METHOD: IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL

       REGULATIONS.    

 

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10. TOXICITY DATA

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ORAL RAT LD50: > 20 gm/kg.

CARCINOGEN:

NTP:     NO

IARC:   NO

METALLIC TIN IS RELATIVELY NON-TOXIC. EXPOSURE TO

DUST OR FUMES OF INORGANIC TIN SALTS IS KNOWN TO

CAUSE BENIGN INFLAMMATION OF THE LUNG TISSUE, A

CONDITION IN WHICH THERE IS NO DISTINCTIVE FIBROSIS,

NO SIGN OF DISABILITY, NO COMPLICATING FACTORS.

 

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11. TRANSPORTATION DATA

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NOT REGULATED

HAZARD CLASS:   NONE

ADR//RID CLASS:  NOT REGULATED

IMDG CLASS:  NOT REGULATED

AIR TRAN. ICAO/IATA CLASS:       REGULATED

MARITIME TRAN. IMDG CLASS:    NOT REGULATED

 

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12. OTHER INFORMATION

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THIS SAFETY DATA SHEET SHOULD BE USED IN CONJUNCTION WITH TECHNICAL SHEETS. IT DOES NOT REPLACE THEM. THE INFORMATION GIVEN IS BASED ON OUR KNOWLEDGE OF THIS PRODUCT, AT THE TIME OF PUBLICATION. IT IS GIVEN IN GOOD FAITH. THE ATTENTION OF THE USER IS DRAWN TO THE POSSIBLE RISKS INCURRED BY USING THE PRODUCT FOR ANY OTHER PURPOSE OTHER THAN THAT FOR WHICH IT WAS INTENDED. THIS DOES NOT IN ANY WAY EXCUSE THE USER FROM KNOWING AND APPLYING ALL THE REGULATIONS GOVERNING HIS ACTIVITY. IT IS THE SOLE RESPONSIBILITY OF THE USER TO TAKE ALL PRECAUTIONS REQUIRED IN HANDLING THE PRODUCT. THE AIM OF THE MANDATORY REGULATIONS MENTIONED IS TO HELP THE USER TO FULFILL HIS OBLIGATIONS REGARDING THE USE OF HAZARDOUS PRODUCTS.